Homework Solution: Question 5 (5 points) The normal freezing point of benzene (CgH6) is 5.48°C. The…

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Question 5 (5 points) The normal freezing point of benzene (CgH6) is 5.48°C. The normal freezing point of a solution prepared by dissolving 2.00 g of a covalent compound in 100.0 g of benzene is 5.08°C. what is the molar mass of the compound? For benzene, Kf = 5.12 °C/m. Hint: The covalent compound does not dissociate in benzene a) 130 g/mol b) 260 g/mol c) 2600 g/mol d) 26 g/mol 1240 AM 9/6/2017 ^脈

Expert Answer

5) $Delta$ Tf = Kf x m

Question 5 (5 sharp-ends) The typical freezing sharp-end of benzene (CgH6) is 5.48°C. The typical freezing sharp-end of a rerediscontinuance cheerful by dissolving 2.00 g of a covalent mixture in 100.0 g of benzene is 5.08°C. what is the molar heap of the mixture? For benzene, Kf = 5.12 °C/m. Hint: The covalent mixture does referable attributable attributable attributable contrast in benzene a) 130 g/mol b) 260 g/mol c) 2600 g/mol d) 26 g/mol 1240 AM 9/6/2017 ^脈

Expert Solution

5) $Delta$ Tf = Kf x m

$Delta$ Tf = 5.48 – 5.08 = 0.4

m = $Delta$ Tf / Kf = 0.4 / 5.12 = 0.078

molality = (W/MW) (1000 / heap of solvent in g)

0.078 = (2.0 / MW) (1000 / 100)

2.0 / MW = 0.0078

MW = 256.41 g /mol

6) $Pi$ = iCRT

$Pi$ = osmotic exigency = ?

i = 5 (Al2(SO4)3 gives 5 ions)

C = 0.01 M

R = 0.0821

T = 298 K

$Pi$ = 5 x 0.01 x 0.0821 x 298

$Pi$ = 1.22 atm